Journal article
Xueming Dong, H. Mayes, K. Morreel, R. Katahira, Yanding Li, J. Ralph, B. Black, G. Beckham
ChemSusChem, 2022
ChemSusChem, 2022
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APA
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Dong, X., Mayes, H., Morreel, K., Katahira, R., Li, Y., Ralph, J., … Beckham, G. (2022). Energy-resolved mass spectrometry as a tool for identification of lignin depolymerization products. ChemSusChem.
Chicago/Turabian
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Dong, Xueming, H. Mayes, K. Morreel, R. Katahira, Yanding Li, J. Ralph, B. Black, and G. Beckham. “Energy-Resolved Mass Spectrometry as a Tool for Identification of Lignin Depolymerization Products.” ChemSusChem (2022).
MLA
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Dong, Xueming, et al. “Energy-Resolved Mass Spectrometry as a Tool for Identification of Lignin Depolymerization Products.” ChemSusChem, 2022.
BibTeX Click to copy
@article{xueming2022a,
title = {Energy-resolved mass spectrometry as a tool for identification of lignin depolymerization products.},
year = {2022},
journal = {ChemSusChem},
author = {Dong, Xueming and Mayes, H. and Morreel, K. and Katahira, R. and Li, Yanding and Ralph, J. and Black, B. and Beckham, G.}
}
Abstract
<p class="Footnote" style="margin: 0in 0in 30pt; text-indent: 0in; line-height: 11.25pt; font-size: 7pt; font-family: Arial, sans-serif; color: rgb(0, 0, 0); text-align: justify;"><span style="font-size: 8pt;">Lignin is the largest source of bio-based aromatic compounds in nature, and its valorization is essential to the sustainability of lignocellulosic biorefining. Characterizing lignin-derived compounds remains challenging due to the heterogeneity of this biopolymer. Tandem mass spectrometry is a promising tool for lignin structural analytics, as fragmentation patterns of model compounds can be extrapolated to identify characteristic moieties in complex samples. This work extends previous resonance excitation type collisionally activated dissociation (CAD) methods that identified lignin oligomers containing β–O–4, β–5, and β–β bonds, to also identify characteristics of 5–5, β–1, and 4–O–5 dimers, enabled by beam type CAD with energy-resolved mass spectrometry (ERMS). Overall, beam type ERMS offers in-depth structural information and could ultimately contribute to tools for high-throughput lignin dimer identification.</span><span style="font-size: 8pt;"><o:p>/o:p</span></p>.
